IMPACTS OF PETROLEUM PRODUCTION ON GROUND AND SURFACE WATERS: RESULTS FROM THE OSPER "B" SITE, OSAGE COUNTY, OKLAHOMA

Yousif Kharaka*
Gil Ambats

U. S. Geological Survey
Mail stop-427
345, Middlefield Rd.
Menlo Park, CA 94025
Voice: 650-329-4535
Fax: 650-329-4538
E-mail: ykharaka@usgs.gov

Marvin M. Abbott
U. S. Geological Survey
Oklahoma City, OK 73116

We are involved in a multidisciplinary investigation to study the transport, fate, natural attenuation and ecosystem impacts of inorganic salts, organic compounds and radionuclides present in releases of produced water and associated hydrocarbons at the Osage-Skiatook Petroleum Environmental Research (OSPER) "A" (depleted) and "B" (active) sites, located in Osage County, Oklahoma. About 1.0 hectare of land at the OSPER "B" site is affected by salt scarring, soil salinization and brine and petroleum contamination due to the leakage of produced water and associated hydrocarbons from brine pits and accidental releases from active and inactive tank batteries. Geochemical data collected from nearby oil wells show that the produced water source is a Na-Ca-Cl brine (~150,000 mg/L TDS), with high concentrations of Mg and Sr, but low SO4.

More than 100 water samples have been obtained from OSPER "B" site; from the two brine pits, several brine pools and seeps, local streams, Skiatook Lake, and from 40 boreholes (1-71 m deep), recently drilled and completed. Results show diluted brine (up to ~25,000 mg/L TDS) and minor amounts of oil flow from the brine pits through the shallow eolian sand, colluvial and alluvial deposits towards the Skiatook Lake, a 4250-hectare reservoir that provides drinking water to the local communities and is used as a recreational fishery. Preliminary results from four relatively deep wells completed in May 2004 clearly show that produced-water brine and minor oil have penetrated the thick (3.5-6 m) shale unit and contaminated the underlying aquifers. The chemical composition of released brine is modified by sorption, mineral precipitation/dissolution, transpiration, volatilization and bacterially mediated oxidation/reduction reactions, in addition to mixing with percolating precipitation water, lake water and pristine groundwater.